nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
2017, 02, v.34;No.197 75-82
二氧化碳还原技术研究进展
基金项目(Foundation):
邮箱(Email):
DOI:
摘要:

综述了CO2催化氢化、电化学还原、光催化还原、光电催化还原以及饱和烃类氧化脱氢等CO2还原技术的研究进展,并指出CO2还原技术今后的研究方向。

Abstract:

Various typical CO2 reduction technologies were reviewed,such as catalytic hydrogenation of CO2,electrocatalytic CO2 reduction,photocatalytic CO2 reduction,photoelectrocatalytic CO2 reduction and oxidation of saturated hydrocarbon by CO2,and also shows the research directions of CO2 reduction technologies in the future.

参考文献

[1]Nicola K,Christopher J W,Arjan W K.Stereoselective Synthesis with Carbon Dioxide[J].Adv Synth Catal,2013,355:2115-2138.

[2]Chihiro M,Yuki M,Tadashi E.Recent progress in catalytic conversions of carbon dioxide[J].Catal Sci Technol,2014,4:1482-1497.

[3]Ioanna D,Pelayo G G,Rachael H E,et al.Carbon dioxide utilization for production of transport fuels:process and economic analysis[J].Energy Environ Sci,2015,8:1775-1789.

[4]Rosa M C,Adisa A.Carbon capture,storage and utilisation technologies:A critical analysis and comparison of their life cycle environmental impacts[J].Journal of CO_2Utilization,2015,9:82-102.

[5]Farnaz T Z,Saeed S,Maryam T R.Conversion of carbon dioxide to valuable petrochemicals:An approach to clean development mechanism[J].Journal of Natural Gas Chemistry,2011,20(3):219-231.

[6]孙洪志,王倩,宋名秀,等.CO_2化学利用的研究进展[J].化工进展,2013,32(7):1666-1672.

[7]Morris A J,Meyer G J,Fujita E.Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels[J].Acc Chem Res,2009,42(12):1983-1994.

[8]Gao J J,Wang Y L,Ping Y,et al.A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas[J].RSC Advances,2012,2:2358-2368.

[9]Lu B W,Kawamoto K.Preparation of the highly loaded and well-dispersed NiO/SBA-15for methanation of producer gas[J].Fuel,2013,103:699-704.

[10]Zhou G L,Wu T,Zhang H B,et al.Carbon dioxide methanation on ordered mesoporous Co/KIT-6catalyst[J].Chem Eng Commun,2014,201(2):233-240.

[11]Karelovic A,Ruiz P.Mechanistic study of low temperature CO_2 methanation over Rh/TiO2 catalysts[J].J Catal,2013,301:141-153.

[12]Tada S,Ochieng O J,Kikuchi R,et al.Promotion of CO_2methanation activity and CH4selectivity at low temperatures over Ru/CeO2/Al2O3catalysts[J].Int J Hydrogen Energy,2014,39:10090-10100.

[13]Park J N,McFarland E W.A highly dispersed Pd-Mg/SiO2catalyst active for methanation of CO_2[J].J Catal,2009,266:92-97.

[14]刘华平,叶素芳,孔丽萍,等.镍基催化剂的二氧化碳甲烷化催化性能[J].化工生产与技术,2015,22(6):41-49.

[15]职国娟,王英勇,靳国强,等.第二金属组分对Ni/SiC催化剂CO_2甲烷化性能的影响[J].天然气化工(C1化学与化工),2016,41(1):24-28.

[16]Wilkinson S K,van de Water L G A,Miller B.Understanding the generation of methanol synthesis and water gas shift activity over copper-based catalysts—A spatially resolved experimental kinetic study using steady and nonsteady state operation under CO/CO_2/H2 feeds[J].J Catal,2016,337:208-220.

[17]常佳,阮艳军.二氧化碳加氢催化合成甲醇的研究进展[J].当代化工,2015,40(11):2621-2624.

[18]郭晓明,毛东森,卢冠忠,等.CO_2加氢合成甲醇催化剂的研究进展[J].化工进展,2012,31(3):477-488.

[19]于杨.轻稀土元素改性Cu/ZnO/Al2O3催化剂对CO_2加氢制甲醇反应的催化性能[J].石油化工,2016,45(1):24-30.

[20]Zhang Y P,Fei J H,Yu Y M,et al.Study of CO_2hydrogenation to methanol over Cu-V/γ-Al2O3 catalyst[J].Journal of Natural Gas Chemistry,2007,16:12-15.

[21]Stoczynski J,Grabowski R,Olszewski P,et al.Effect of metal oxide additives on the activity and stability of Cu/ZnO/ZrO2catalysts in the synthesis of methanol from CO_2and H2[J].Applied Catalysis:General,2006,310:127-137.

[22]梁雪莲.CO_2加氢制甲醇用Pd-修饰MWCNTs-促进高效新型Pd-ZnO催化剂的研究[D].厦门大学,2009.

[23]Ota A,Kunkes E L,Kasatkin I,et al.Comparative study of hydrotalcite-derived supported Pd2Ga and PdZn intermetallic nanoparticles as methanol synthesis and methanol steam reforming catalysts[J].J Catal,2012,293:27-38.

[24]秦祖赠,刘瑞雯,纪红兵,等.二氧化碳的活化及其催化加氢制二甲醚的研究进展[J].化工进展,2015,34(1):119-126.

[25]Yang Y X,White M G,Liu P.Theoretical Study of Methanol Synthesis from CO_2 Hydrogenation on Metal-Doped Cu(Ⅲ)Surfaces[J].J Phys Chem C,2012,116(1):248-256.

[26]Flores J H,Peixoto D P B,Appel L G,et al.The influence of different methanol synthesis catalysts on direct synthesis of DME from syngas[J].Catal Today,2011,172(1):218-225.

[27]梁兵连,段洪敏,侯宝林,等.二氧化碳加氢合成低碳烯烃的研究进展[J].化工进展,2015,34(10):3746-3754.

[28]向航,李静,曹建新,等.CO_2绿色化合成低碳烯烃Fe基催化剂研究进展[J].现代化工,2015,35(2):27-32.

[29]丁凡舒,聂小娃,刘民,等.Fe基催化剂上二氧化碳加氢制C+2烃的研究进展[J].应用化学,2016,33(2):123-132.

[30]王影,彭闯,蒋登高.电化学方法固定二氧化碳的研究进展[J].现代化工,2013,33(10):37-41.

[31]Wang C C,Zhang Y Q,Li J,et al.Photocatalytic CO_2reduction in metal-organic frameworks:A mini review[J].J Mol Struct,2015,1083(5):127-136.

[32]吴改,程军,张梦,等.太阳能光电催化还原CO_2的最新研究进展[J].浙江大学学报:工学版,2013,47(4):680-687.

[33]Qiao J,Liu Y,Hong F,et al.A review of catalysts for the electroreduction ofcarbon dioxide to produce low-carbon fuels[J].Chem Soc Rev,2014,43(2):631-675.

[34]Shoko A,Kentaro Me,Kei O,et al.Selective electrochemical reduction of CO_2 to CO with a cobalt chlorin complex adsorbed on multi-walled carbon nanotubes in water[J].Chem Commun,2015,51:10226-10228.

[35]Kang X H,Zhu Q G,Sun X F,et al.Highly efficient electrochemical reduction of CO_2to CH4in an ionic liquid using a metal–organic framework cathode[J].Chem Sci,2016,7:266-273.

[36]Varela A S,Kroschel M,Reier T,et al.Controlling the selectivity of CO_2electroreduction on copper:The effect of the electrolyte concentration and the importance of the local pH[J].Catal Today,2016,260:8-13.

[37]张现萍,黄海燕,靳红利,等.水溶液中电化学还原CO_2研究进展[J].化工进展,2015,34(12):4139-4144.

[38]王静.多孔锡电极的制备及其用于CO_2电化学还原性能的研究[D].天津大学,2014.

[39]Chai G L,Guo Z X.Highly effective sites and selectivity of nitrogen-doped graphene/CNT catalysts for CO_2 electrochemical reduction[J].Chem Sci,2016,7:1268-1275.

[40]范梦阳.纳米氧化铜、氧化锡及其复合物(CuO-Cu2O、SnO2、SnO2-CuO)的制备及CO_2电催化还原性能[D].东华大学,2015.

[41]赵晨辰,何向明,王莉,等.电化学还原CO_2阴极材料研究进展[J].化工进展,2013,32(2):373-380.

[42]秦军荣.基于金属纳米粒子修饰电极在吡啶水溶液中电催化还原CO_2的研究[D].上海师范大学,2015.

[43]吕伟欣.二氧化碳在乙腈和水中的电化学还原[D].东南大学,2014.

[44]Kumar R S,Kumar S S,Kulandainathan M A.Highly selective electrochemical reduction of carbon dioxide usin g Cu based metal organic framework as an electrocatalyst[J].Electrochem Commun,2012,25:70-73.

[45]Kaneco S,Katsumata H,Suzuki T,et al.Electrochemical reduction of carbon dioxide to ethylene at a copper electrode in methanol using potassium hydroxide and rubidium hydroxide supporting electrolytes[J].Electrochim Acta,2006,51(16):3316-3321.

[46]Oh Y J,H X l.Organic molecules as mediators and catalysts for photocatalytic and electrocatalytic CO_2reduction[J].Chem Soc Rev,2013,42(6):2253-2261.

[47]Carlesi C,Carvajal D,Vasquez D,et al.Analysis of carbon dioxide-to-methanol direct electrochemical conversion mediated by an ionic liquid[J].Chem Eng Process,2014,85(11):48-56.

[48]Zhou F,Liu S M,Yang B Q,et al.Highly selective and stable electro-catalytic system with ionic liquids for the reduction of carbon dioxide to carbon monoxide[J].Electrochem.Commun.,2015,55(6):43-46.

[49]王超,陈达,刘姝,等.TiO2光催化还原CO_2研究进展.材料导报:A,2011,25(7):38-4 6.

[50]Lo C C,Hung C H,Yuan C S,et al.Photoreduction of carbon dioxide with H2and H2O over TiO2arid ZrO2in a circulated photocatalytic reactor[J].Sol Energy Mater Sol Cells,2007,91(19):1765.

[51]Dey G R,Belapurkarb A D,Kishore K.Photocatalytic reduction of carbon dioxide to methane using TiO2as suspension in water[J].J Photochem Photobiol,A:Chem,2004,163:503-508.

[52]Kocf K,ZatloukalováK,ObalováL,et al.Wave length effect on photocatalytic reduction of CO_2by Ag/TiO2catalyst[J].Chin J Catal,2011,32(5):812-815.

[53]Li X Z,Li F B,Yan g C L,et al.Photo-cata lytic activ ity of WOx-TiO2under visible light Irradiation[J].J Photochem Photobiol,A:Chem,2001,141:209-217.

[54]李娜.石墨烯基半导体纳米复合材料的制备及其在光催化还原CO_2中的应用[D].中北大学,2015.

[55]徐金凤.基于TiO2和CuO高效光电催化剂的构建及其光电协同催化还原CO_2的研究[D].山东农业大学,2014.

[56]Li P,Zhao G,Zhao K,Gao J,et al.An efficient and energy saving approach to photocatalytic degradation of opaque high-chroma methylene blue wastewater by electrocatalytic pre-oxidation[J].Dyes and Pigment,2012,92:923-928.

[57]Kaneco S,Katsumata H,Suzuki T,et al.Photoelectrochemical reduction of carbon dioxide at p-type gallium arsenide and p-type indium phosphide electrodes in methano1[J].Chem Eng J,2006,116:227-231.

[58]Hirota K,Tryk D A,Yamamoto T,et al.Photoelectrochemical reduction of CO_2in a high-pressure CO_2 plus methano1medium at p-type semiconductor electrodes[J].J Phys Chem B,1998,102(49):9834-9843.

[59]Flaisher H,Tenne R,Halmann M.Photo-electrochemical reduction of carbon dioxide in aqueous solutions on p-GaP electrodes:an ac impedance study with phase-sensitive detection[J].J Electroanal Chem,1996,402(1/2):97-105.

[60]Kumar B,Llorente M,Froehlich J,et al.Photochemical and photoelectrochemical reduction of CO_2[J].Annu Rev Phys Chem,2012,63:541-569.

[61]Le M,Ren M,Zhang Z,et al.Electrochemical reduction of CO_2to CH3OH at copper oxide surfaces[J].J Electrochem Soc,2011,158:E45-E49.

[62]Barton E E,Rampulla D M,Bocarsly A B.Selective solar-driven reduction of CO_2to methanol using a catalyzed P-GaP based photoelectrochemical cell[J].J Am Chem Soc,2008,130:6342-6344.

[63]Chai S,Zhao G,Li P,Lei Y,et al.Novel sieve-like SnO2/TiO2nanotubes with integrated photoelectrocatalysis:fabrication and application for efficient toxicity elimination of nitrophenol wastewater[J].J Phys Chem C,2011,115:18261-18269.

[64]Wang S B,Liu G Q.Reforming of methane with carbon dioxide over Ni/Al2O3catalysts:effect of nickel precursor[J].Appl Phys A:General,1998,169(2):271-280.

[65]Li J M,Huang F Y,Weng W Z,et al.Effect of Rh loading on the performance of Rh/Al2O3for methane partial oxidation to synthesis gas[J].Catal Today,2008,131(1-4):179-187.

[66]OConnor A M,Ross J R.The effect of O2addition on the carbon dioxide reforming of methane over Pt/ZrO2catalysts[J].Catal Today,1998,46(2-3):203-210.

[67]Wilcox E M,Roberts G W,Spivey J J.Direct catalytic formation of acetic acid from CO_2and methane[J].Catal Today,2003,88(1-2):83-90.

[68]Rostrup-Nielsen J R,Bak Hansen J H.CO_2-reforming of methane over transition metals[J].J Catal,1993,144(1):38-49.

[69]Qin D,Lapszewicz J.Study of mixed steam and CO_2reforming of CH4to syngas on MgO-supported metals[J].Catal Today,1994,1(2-3):551-560.

[70]李建发.中孔镍基催化材料调控制备及在CH4/CO_2重整反应中的性能研究[D].天津大学,2014.

[71]Wang S B,Murata K,Hayakawa T,et al.Dehydrogenation of ethane with carbon dioxide over supported chromium oxide catalysts[J].Appl Catal,A:General,2000,196(1):1-8.

[72]Mimura N,Takahara I,Inaba M,et al.High-performance Cr/H-ZSM-5catalysts for oxidative dehydrogenation of ethane to ethylene with CO_2as an oxidant[J].Catal Commun,2002,3(6):257-262.

[73]Fujdala K,Tilley T D.Thermolytic molecular precursor routes to Cr/Si/Al/O and Cr/Si/Zr/O catalysts for the oxidative dehydrogenation and dehydrogenation of propane[J].J Catal,2003,218(1):123-134.

[74]Takehira K,Ohishi Y,Shishido T,et al.Behavior of active sites on Cr-MCM-41catalysts during the dehydrogenation of propane with CO_2[J].J Catal,2004,224(2):404-416.

[75]赵新红,李顺清,王晓来,等.制备方法对Cr/Si-2催化剂在CO_2氧化乙烷脱氢制乙烯反应中的催化性能的影响[J].分子催化,2007,21(2):132-138.

基本信息:

中图分类号:O643.3

引用信息:

[1]李军,崔凤霞,李荣.二氧化碳还原技术研究进展[J].精细石油化工,2017,34(02):75-82.

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文