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分离CO2是当前能源和环境领域最重要的课题之一,与传统方法相比,膜分离法由于具有投资少、能耗低且环境友好等优点备受关注。介绍了CO2膜分离技术的原理、传递机制、工艺流程,着重论述了国内外各种CO2膜分离技术的工作原理、研究现状,应用条件及优缺点,并对各种膜的发展方向进行了展望。
Abstract:CO2separation is one of the most important subjects on energy and environment.Compared with conventional CO2 separation processes,membrane technology for CO2 separation has been attracting more and more attention due to low investment,low energy consumption and environmental friendliness.The principles of CO2 separation,transport mechanism and technological process have been introduced.The different types of membranes available for CO2 separation including their working principles,current status,application conditions and their advantages and drawbacks were mainly described,and future development trends for CO2 separation membranes were also discussed.
[1]冯世超,任吉中,任晓灵,等.聚醚共聚酰胺/聚乙二醇共混膜的制备及其气体渗透性能的研究[J].膜科学与技术,2012,32(5):27-33.
[2]Mansourizadeh A,Ismail A F,Abdullah M S,et a1.Preparation of polyvinyliden fluoride hollow fiber membranes for CO2 absorption using phaseinversion promoter additives[J].Journal of Membrane Science,2010,355:200-207.
[3]Li J L,CHEN B H.Review of CO2absorption using chemical solvents in hollow fiber membrane contactors[J].Separation and Purification Technology,2005,41:109-122.
[4]Zhou J,Ho W S.CO2-selective polymeric membranes containing amines in crosslinked polyvinyl alcohol[J].Journal of Membrane Science,2006,286:310-321.
[5]朱玲.水合物膜法分离二氧化碳实验研究[D].大连理工大学,2010.
[6]Kovvali A S,Sirkar K K.Carbon dioxide separation with novel solvents as liquid membranes[J].Industrial and Engineering Chemistry Research,2002,41(9):2287-2295.
[7]Robeson L M.The Upper Bound Revisited[J].Journal of Membrane?Science,2008,320:390-400.
[8]廖传华,徐南平,时钧.气体分离无机膜的应用及研究进展[J].中国陶瓷,2003,39(2):15-17.
[9]Scholes C A,Kentish S E,Stevens G W.Carbon dioxide separation through polymeric membrane systems for flue gas application[J].Recent Patents on Chemical Engineering,2008,1(1):52-66.
[10]Cui Y,Kita H,Okamoto K.Preparation and gas separation performance of zeolite T membrane[J].Journal of Materials Chemistry,2004,14(5):924-932.
[11]Othman M R,Tan S C,Bhatia S.Separability of carbon dioxide from methane using MFI zeolite-silicafilmdeposited ongamma-alumina support[J].Microporous and Mesoporous Materials,2009,121:138–144.
[12]Zhu W,Hrabanek P,Gora L,et al.Role of adsorption in the permeation of CH4and CO2through a silicalite-1membrane[J].Industrial and Engineering Chemistry Research,2006,45:767-776.
[13]Zhu X F,Wang H B,Lin Y S.Effect of the membranequality on gas permeation and chemical vapor deposition modification of MFI-Type zeolite membranes[J].Industrial and Engineering Chemistry Research,2010,49:10026-10033.
[14]Li S G,Fan C Q.High-flux SAPO-34 membrane for CO2/N2separation[J].Industrial and Engineering Chemistry Research,2010,49:4399-4404.
[15]Carreon M A,Li S,Falconer J L,et al.Alumina-supported SAPO-34 membranes for CO2/CH4 separation[J].Journal of the American Chemical Society,2008,130:5412-5413.
[16]Himeno S,Tomita T,Suzuki K,et al.Synthesis and permeation properties of a DDR-type zeolite membrane for separation of CO2/CH4gaseous mixtures[J].Industrial and Engineering Chemistry Research,2007,46:6989-6997.
[17]Anderson M Lin Y S.Carbonate-ceramic dual-phase membrane for carbon dioxide separation[J].Journal of Membrane Science,2010,357:122–129.
[18]张瑞波.煤电及石化企业CO2减排技术[J].能源环境保护,2010,24(6):9-12.
[19]Stern S A.Polymers for gas separations:The next decade[J].Journal of Membrane Science,1994,94:1-65.
[20]Illing G,Hellgardt K,Wakeman R J,et al.Preparation and characterization of polyaniline based membranes for gas separation[J].Journal of Membrane Science,2001,184:69-78.
[21]Xu Z K,Dannenberg C,Springer J,et al.Novel poly(arylene ether)as membranes for gas separation[J].Journal of Membrane Science,2002,205:23-31.
[22]Pixton M R,Paul D R.Gas transport properties of polyarylates.Part I:Connector and pendant group effects[J].Journal of Polymer Science Part B:Polymer Physics,1995,33(7):1135-1149.
[23]Aguilar-Vega M,Paul D R.Gas transport properties of polycarbonates and polysulfones with aromatic substitutions on the bisphenol connector group[J].Journal of Polymer Science,Part B:Polymer Physics,1993,31(11):1599-1610.
[24]Li Y,Ding M,Xu J.Gas separation properties of aromatic polyetherimides from 1,4-bis(3,4-dicarboxyphenoxy)benzene dianhydride and 3,5-diaminobenzic acid or its esters[J].Journal of Applied Polymer Science,1997,63(1):1-7.
[25]Lin H,Freeman B D.Gas solubility,diffusivity and permeability in poly(ethylene oxide)[J].Journal of Membrane Science,2004,239:105-117.
[26]Zimmerman C M,Koros W J.Entropic selectivity analysis of a series of polypyrolones for gas separation membranes[J].Macromolecules,1999,32(10):3341-3350.
[27]Aitken C L,Koros W J,Paul D R.Effect of structural symmetry on gas transport properties of polysulfones[J].Macromolecules,1992,25(13):3424-3434.
[28]Han S H,Lee J E,Lee K J,et al.Highly gas permeable and microporous polybenzimidazole membrane by thermal rearrangement[J].Journal of Membrane Science,2010,357:143-151.
[29]Houde A Y,Krishnakumar B,Charati S G,et al.Permeability of dense(homogeneous)cellulose acetate membranes to methane,carbon dioxide,and their mixtures at elevated pressures[J].Journal of Applied Polymer Science,1996,62:2181-2192.
[30]Liu Y,Wang R,Chung T S.Chemieal cross-linking modifieation of polyimide membranes for gas separation[J].Journal of Membrane Science,2001,189:231-239.
[31]Vaughn J T,Koros W J,Johnson J R,et al.Effect of thermal annealing on a novel polyamide-imide polymer membrane for aggressive acid gas separations[J].Journal of Membrane Science,2012,401:163-174.
[32]Dong G,Li H,Chen V.Factors affect defect-free Matrimid?hollow fiber gas separation performance in natural gas purification[J].Journal of Membrane Science,2010,353(1):17-27.
[33]Li F Y,Li Y,Chung T S,et al.Development and positron annihilation spectroscopy(PAS)characterization of polyamide imide(PAI)-polyethersulfone(PES)based defect-free dual-layer hollow fiber membranes with an ultrathin dense-selective layer for gas separation[J].Journal of Membrane Science,2011,378:541-550.
[34]Bos A,Piint I G M,Wessling M,et al.Suppression of CO2-plasticization by semiinterpenetrating polymer network formation[J].Journal of Polymer Science,Part B:Polymer Physics,1998,36(9):1547-1556.
[35]Kim T J,Baoan L I,Hagg M B.Novel fixed-site-carrier polyvinylamine membrane for carbon dioxide capture[J].Journal of Polymer Science,Part B:Polymer Physics,2004,42:4326-4336.
[36]Ward W J,Robb W L.Cabron dioxide-oxygen separation:facilitated transport of carbon dioxide across a liquid film[J].Science,1967,156:1481-1484.
[37]Chen H,Skovvalk A,Majumdar S.Seleetive CO2separationt from CO2-N2 Mixture by immobilized carbonate-glyeerol membranes[J].Industrial and Engineering Chemistry Research,1999,38(9):3489-3498.
[38]Pez G P,Cariin R T,Laciak D V,et al.Method for gas sepearation:US,4761161[P].1988-08-02.
[39]Leblanc O H,Ward W J,Matson S L,et al.Faeilitated transport in ion-exchange membranes[J].Journal of Membrane Science,1980,6:339-343.
[40]Matsuyama H,Masaaki,Termaoto,et al.Development of a new functional cation-exchange membrane and its application to facilitated transport of CO2[J].Journal of Membrane Science,1994,93:237-244.
[41]Sandru M,Haukeb S H,Hgg M B.Composite hollow fiber membranes for CO2capture[J].Journal of Membrane Science,2010,346:172-186.
[42]Zhao Y N,Winston Ho W S.CO2-selective membranes containing sterically hindered amines for CO2/H2Separation[J].Industrial and Engineering Chemistry Research,2013,52:8774-8782.
[43]Yan S P,Fang M X,Zhang W F,et al.Experimental study on the separation of CO2from flue gas using hollow fiber membrane contactors without wetting[J].Fuel Processing Technology,2007,88:501-511.
[44]Zhang Q,Cussler E L.Hollow fiber gas membranes[J].AIChE Journal,1985,31:1548-1553.
[45]RiemerP W F,Ormerod W G.lnternational perspectives and the results of carbon dioxide capture disposal and utilization studies[J].Energy Conversion and Management,1995,36(6-9):813-818.
[46]Wang R,Zhang H Y,Feron P H M,et aI.Influence of membrane wetting on CO2capture in microporous hollow fiber membrane contactors[J].Separation and Purification Technology,2005,46:33-40.
[47]Dindore V Y,Brilman D W F,Geuzebroek F H,et al.Membrane-solvent selection for CO2removal using membrane gas-liquid contactors[J].Separation and Purification Technology,2004,40:133-145.
[48]Bakeri G,Matsuura T,Ismail A F,et al.A novel surface modified polyetherimide hollow fiber membrane for gas–liquid contacting processes[J].Separation and Purification Technology 2012,89:160-170.
[49]Tantekin-Ersolmaz S B,Atalay-Oral C,Tatlier M,et al.Effect of zeolite particle size on the performance of polymerzeolite mixed matrix membranes[J].Journal of Membrane Science,2000,175:285–288.
[50]宫晓娜,朱利平,徐又一,等.碳纳米管在分离膜材料中的应用[J].膜科学与技术,2011,31(5):89-93.
[51]Xu N,Li X,Franks M A.Silver-molten carbonate composite as a new high-flux membrane for electrochemical separation of CO2from flue gas[J].Journal of Membrane Science,2012,401:190-194.
[52]Kong Y,Du H,Yang J,et al.Study on polyimide/TiO2nanocomposite membranes for gas separation[J].Desalination,2002,146(1):49-55.
[53]Karatay E,Kalipfilar H,Yilmaz L.Preparation and performance assessment of binary and ternary PES-SAPO 34-HMA based gas separation membranes[J].Journal of Membrane Science,2010,364(1):75-81.
[54]Sharif A,Koolivand H,Khanbabaie G,et al.Improvement of CO2/CH4separation characteristics of polyethersulfone by modifying with polydimethylsiloxane and nanosilica[J].Journal of Polymer Research,2012,19(7):1-8.
[55]Jiang LY,Chung T S,Kulprathipanja S.Fabrication of mixed matrix hollow fibers with intimate polymer-zeolite interface for gas separation[J].AIChE Journal,2006,52:2898-2908.
[56]Hosseini S S,Li Y,Chung T S,et al.Enhanced gas separation performance of nanocomposite membranes using MgO nanoparticles[J].Journal of Membrane Science,2007,302:207-217.
[57]Venna S R,Carreon M A.Amino-Functionalized SAPO-34 Membranes for CO2/CH4and CO2/N2Separation[J].Langmuir,2011,27:2888-2894.
[58]Wu H,Li X Q,Li Y F,et al.Facilitated transport mixed matrix membranes incorporated with amine functionalized MCM-41for enhanced gas separation properties[J].Journal of Membrane Science,2014,465:78-90.
[59]Wu T T,Xue Q Z,Ling C C,et al.Fluorine-modified porous graphene as membrane for CO2/N2 separation:molecular dynamic and first-principles simulations[J].The Journal of Phsical Chemistry,2014,118:7369-7376.
[60]Atci E,Keskin S.Understanding the potential of zeolite imidazolate framework membranes in gas separations using atomically detailed calculations[J].The Journal of Phsical Chemistry,2012,116:15525-15537.
基本信息:
DOI:
中图分类号:TQ028.8
引用信息:
[1]曹映玉,杨恩翠,王文举.二氧化碳膜分离技术[J].精细石油化工,2015,32(01):53-60.
基金信息:
天津师范大学博士基金(52XB1111);; 天津市教委重点项目(2012ZD02)