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双酚F主要用于合成环氧树脂和聚碳酸酯,通常采用磷酸作为催化剂合成,但磷酸会严重设备腐蚀。固体酸催化剂腐蚀性小、易分离,可循环利用。综述了固体酸催化剂在合成双酚F中的研究进展,包括分子筛催化剂、磷钨酸催化剂、树脂催化剂、MOF催化剂、天然黏土催化剂等。
Abstract:Bisphenol F is an important chemical intermediate mainly used for the synthesis of epoxy resins and polycarbonate. However, the synthesis of bisphenol F typically uses phosphoric acid as a catalyst, which can lead to severe equipment corrosion. Solid acid catalysts have low corrosiveness, are easy to separate, and can be recycled. This article reviews the research progress of solid acid catalysts in the synthesis of bisphenol F, including molecular sieve catalysts, phosphotungstic acid catalysts, resin catalysts, MOFs-base catalysts, clay catalysts, etc.
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基本信息:
DOI:10.20075/j.cnki.issn.1003-9384.2025.06.018
中图分类号:TQ243.1;TQ426
引用信息:
[1]程铭,孟祥太,谢京燕.固体酸催化剂在合成双酚F中的研究进展[J].精细石油化工,2025,42(06):72-76.DOI:10.20075/j.cnki.issn.1003-9384.2025.06.018.