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综述了MoVTeNbOX催化剂在丙烷选择性氧化制丙烯酸中的研究进展,重点探讨了其晶相结构(M1和M2相)、制备方法(共沉淀法、水热法、喷雾干燥法等)及改性策略(负载、形貌调控、掺杂)对催化性能的影响。阐述了催化剂组成-结构-性能的构效关系。探讨了未来高效稳定催化剂的设计方向,指出通过改进制备条件、优化改性策略,来提升催化剂的氧化还原能力,从而提高丙烷氧化脱氢反应活性和稳定性,为催化剂的规模化生产及工业应用奠定基础。
Abstract:This review summarizes the research progress of MoVTeNbOX catalysts in the selective oxidation of propane to acrylic acid,focusing on the effects of their crystal phase structures(M1 and M2 phases),preparation methods(coprecipitation,hydrothermal synthesis,spray drying,etc.),and modification strategies(supporting,morphology control,doping) on catalytic performance.It elaborates on the structure-activity-performance relationships of the catalysts.The review also discusses future directions for designing highly efficient and stable catalysts,pointing out that improving preparation conditions and optimizing modification strategies can enhance the redox ability of the catalysts,thereby improving the activity and stability of propane oxidative dehydrogenation,laying the foundation for the scale-up production and industrial application of the catalysts.
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基本信息:
DOI:10.20075/j.cnki.issn.1003-9384.2026.02.018
中图分类号:TQ225.131;O643.36
引用信息:
[1]王楠.MoVTeNbO_X催化丙烷选择性氧化制丙烯酸研究进展[J].精细石油化工,2026,43(02):72-76.DOI:10.20075/j.cnki.issn.1003-9384.2026.02.018.
基金信息:
辽宁省科技计划联合计划自然科学基金(2024-MSLH-383); 辽宁省应用基础研究计划(2023JH2/101300243); 辽宁省教育厅基本科研项目(JYTMS20231497)
2026-03-17
2026-03-17