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针对低渗油藏注水开发过程中注水井水驱压力不断升高、注水量欠注严重等问题,采用KH570改性纳米二硫化钼,以CTAB为分散剂制备了一种新型纳米增注剂,评价了其团聚粒径、界面张力、润湿性、长期稳定性及降压增注性能。结果表明:当改性纳米二硫化钼质量分数为0.5%、CTAB质量分数为5%时,可制得溶液平均粒径在90nm的增注剂。在增注剂加量为0.3%时,界面张力降至9.5×10~-3mN/m,石英砂片接触角从40°增至93°,显著改善界面性质与润湿性;对天然岩心注入0.6PV,后续水驱压力下降32.87%,降压效果优于纳米SiO2增注剂(降压率25.6%)。
Abstract:Aiming at the problems of continuously increasing water flooding pressure and serious insufficient injection dur-ing the water flooding development of low-permeability reservoirs, a new type of nano injection enhancer was prepared by modifying nano molybdenum disulfide with KH570 and selecting CTAB as the dispersant. Its agglomerated particle size, interfacial tension, wettability, long-term stability, pressure-reducing, and injection-enhancing performance were evalu-ated through experiments. The results show that when the mass content of modified nano molybdenum disulfide is 0.5% and the mass content of CTAB is 5%, an injection enhancer with an average particle size of 90 nm can be prepared. When the dosage is 0.3%, the interfacial tension decreases to 9.5×10-3 m N/m, and the contact angle of quartz sand increases from 40° to 93°, significantly improve the interfacial properties and wettability. After injecting 0.6 PV of the injection enhancer into the natural core, the subsequent water drive pressure decreases by 32.87%, with a better pressure reduction effect than the nano-SiO2 injection enhancer(with a pressure reduction rate of 25.6%).
[1]吕文斌,王博,曹耀平,等.低渗透油藏注水井纳米微乳液降压增注体系研究[J].当代化工,2022,51(2):371-373.
[2]冯岸洲,张建强,蒋平,等.低渗透油藏高浓度表面活性剂体系降压增注试验研究[J].油田化学,2011,28(1):69-73.
[3]许定达,宁俊杰,唐煜东,等.注水井纳米聚硅多元复合降压增注技术研究[J].钻采工艺,2019,42(3):50-52.
[4]周勤.低渗透油藏纳米乳液降压增注研究[J].油气藏评价与开发,2016,6(6):61-66.
[5]冯辉霞,张建强,张国宏,等. CTAB对二硫化钼粉体的表面改性实验研究[J].化工科技,2008,16(4):9-13.
[6]张建强,冯辉霞,赵霞,等.硬脂酸对二硫化钼粉体的表面改性研究[J].应用化工,2008,37(7):742-745.
[7]杨欢.致密油藏纳米增注体系实验研究[J].新疆石油天然气,2017,13(1):76-81.
[8]王建海,李勇,冯一波,等.改性纳米二氧化硅流体的制备及其降压增注规律[J].石油化工,2023,52(3):352-357.
[9]翟恒来,齐宁,孙逊,等.一种新型纳米SiO2降压增注剂的制备与评价[J].材料导报,2019,33(3):975-979.
[10]李瑞冬,葛际江,李光辉,等.低渗透油田超低界面张力表面活性剂降压增注研究[J].石油与天然气化工,2012,41(4):415-418.
[11]何更生,唐海.油层物理[M]. 2版.北京:石油工业出版社,2011:125-132.
[12]李浩.海水基降压增注用纳米材料的研制及界面吸附规律研究[D].青岛:中国石油大学(华东),2018.
基本信息:
DOI:10.20075/j.cnki.issn.1003-9384.2026.03.002
中图分类号:TE357.6
引用信息:
[1]卢星,李亮.改性纳米二硫化钼增注剂的制备及其性能评价[J].精细石油化工,2026,43(03):4-8.DOI:10.20075/j.cnki.issn.1003-9384.2026.03.002.
2026-05-18
2026-05-18